Case Study: Oxygen Barrier Properties of Recycled PET Bottles
Recycling plastic bottles is vital for environmental protection, but it can affect their oxygen barrier properties, making them less suitable for oxygen-sensitive products. Our case study on PET bottles with varying amounts of recycled material found that increasing the recycled content from 25% to 50% only slightly reduced their oxygen barrier. This suggests that using more recycled material does not significantly compromise the bottles' performance.
The Problem
The growing trend of recycling waste plastic
bottles requires an understanding of how reclaimed materials affect a product's
performance. For PET bottles, a crucial metric is their ability to act as an
oxygen barrier. High oxygen permeability can compromise the quality of packaged
goods, limiting the use of recycled materials in food and beverage containers.
This study aims to quantify that effect by testing bottles with varying
percentages of recycled content.
The Test
Two types of PET bottle samples were tested:
one containing 25% recycled material and another with 50% recycled material.
The testing was conducted using the coulometric method, a standard approach for
measuring the oxygen transmission rate (OTR) of packaging materials, as
outlined in standards such as ASTM F1307-02.
The test conditions were set at a temperature
of 23∘C and a relative humidity of 100% RH to
simulate the environment of liquid-filled bottles. The samples were
meticulously sealed onto a special container-supporter to prevent leakage, then
placed in the test instrument for analysis.
The Instrument
The test was performed using Labthink C230H Oxygen
Transmission Rate Test System, which employs a coulometric sensor to measure
OTR. This system is designed to test both film/sheet samples and container
samples. Key features of the instrument include:
- High
precision: A resolution of 0.001cm3/(m2⋅day) and
a container sample test range of 0.00005−1cm3/(pkg⋅day).
- Automated
control: The system automatically controls and monitors temperature and
humidity within a range of 10−55∘C
and 5−100% RH.
- Versatility:
It can test up to three samples simultaneously and is compatible with a
wide range of materials, including various plastic films, sheets, and
containers like bottles and barrels.
- Data
integrity: The system features a DataShieldTM data protection
system to ensure secure data management.
230H Oxygen Transmission Rate Tester
The test yielded the following results for the
oxygen transmission rates:
- 25%
Recycled Material: 0.01792cm3/(pkg⋅day)
- 50%
Recycled Material: 0.01907cm3/(pkg⋅day)
The findings showed that the OTRs for both
samples were very similar, with the bottle containing 25% recycled material
having a slightly better oxygen barrier property.
Conclusion
The study demonstrates that increasing the
recycled content in PET bottles from 25% to 50% only slightly diminishes their
oxygen barrier properties. The minimal difference suggests that recycled
content, within this range, does not significantly compromise the bottles'
ability to protect oxygen-sensitive products.
This case study also serves as a testament to
the effectiveness of Labthink C230H Oxygen Transmission Rate Test System. Its
precise, automated, and easy-to-use nature makes it a reliable tool for
manufacturers to ensure the quality and performance of packaging materials,
supporting the broader goal of increasing sustainability in the industry.
As the demand for functional packaging
materials grows, testing methods are evolving to ensure a more comprehensive
evaluation of packaging films. Labthink encourages collaboration with packaging
industry companies for quality control! Visit the website www.labthink.com to learn more!


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